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Yukawa, Takuji*; Inoue, Hiroyuki*; Kojima, Takao*; Iwase, Akihiro*; Taniguchi, Naoki; Tachikawa, Hirokazu*
Zairyo To Kankyo 2016 Koenshu (CD-ROM), p.359 - 362, 2016/05
The immersion tests of pure titanium were carried out in aqueous solution containing carbonate/bicarbonate with 50 mM-chloride ion under gamma irradiation. The effect of pH on general corrosion rate of titanium were studied. The experimental results showed that the concentration of hydrogen preoxide was increased with pH, and the corrosion rate increased with the hydrogen preoxide concentration. The corrosion rate in pH12 and 13 were 5 to10 times larger than those under unirradiated conditions.
Saito, Shigeru; Ouchi, Nobuo; Fukaya, Kiyoshi*; Ishiyama, Shintaro; Tsuchiya, Yoshinori; Nakajima, Hideo
JAERI-Tech 2003-027, 63 Pages, 2003/03
Around the super conducting (SC) coils of SC linear accelerator or fusion reactor, several kind of dissimilar materials bond will be needed. In recent years, pure titanium has been proposed as jacket material for SC coil of fusion reactor. Cu-alloys will be used for connection of SC coils. Cryogenic stainless steels have been development for structural material. Therefore, it is necessary to develop new bonding techniques and we started the bonding technology development by hot isostatic press (HIP) method to bond Cu-alloys with titanium and cryogenic stainless steels. In this experiments, optimization of HIP bonding condition and evaluation of bonding strength by metallurgical observation, tensile and bending tests were performed.
Taniguchi, Naoki; Kawasaki, Manabu*; Fujiwara, Kazuo*
JNC TN8400 2001-011, 62 Pages, 2001/03
The corrosion of metallic materials used in natural environment are sometimes affected by microbial action. It is apprehended that microorganism living in deep underground or brought from ground surface during excavation makes an impact on overpack material for geological disposal of high-level radioactive waste. Sulfate reducing bacteria (SRB) is known to be one of the most representative microorganism which affects the corrosion of metals. In this study, the behavior of growth of SRB was investigated at first under the presence of bentonite as a main component of buffer material which encloses the overpack. The results of the tests showed that the population of SRB after the culture in synthetic sea water mixed with bentonite decreased with increasing the ratio of bentonite/solution. SRB was hardly grown in medium whose bentonite/solution ratio exceeded 1000g/l. As a conservative case, the effects of sulfide on the corrosion of overpack materials were also studied assuming high activity of SRB. Carbon steel, copper and titanium specimens were immersed in synthetic sea water purging 0.1MPa HS gas and the corrosion behavior was compared with the results in N gas purging environment. Obvious effect of sulfide on the corrosion of carbon steel was not observed, but the corrosion rates of copper specimens were accelerated several hundred times by purging HS gas. The absorption of hydrogen into titanium specimens was not affected by purging HS gas, but the difference of hydrogen absorption between pure titanium and titanium alloy containing 0.06%-Pd was observed.
Yukawa, Takuji*; Inoue, Hiroyuki*; Kojima, Takao*; Tachikawa, Hirokazu*; Taniguchi, Naoki
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no abstracts in English